paper

Finite field calculations of static polarizabilities and hyperpolarizabilities of In and Sr

arXiv:1501.04439 · doi:10.1103/PhysRevA.92.052515

Abstract

The finite field calculations are performed for two heavy frequency-standard candidates In and Sr. The progressive hierarchy of electron correlations is implemented by the relativistic coupled-cluster and configuration interaction methods combined with basis set of increasing size. The dipole polarizabilities, dipole hyperpolarizabilities, quadrupole moments, and quadrupole polarizabilities are recommended for the ground state 5s and low-lying states 5s5p of In and Sr. Comparative study of the fully and scalar relativistic electron correlation calculations reveals the effect of the spin-orbit interaction on the dipole polarizabilities of In and Sr. Finally, the blackbody-radiation shifts due to the dipole polarizability, dipole hyperpolarizability, and quadrupole polarizability are evaluated for the clock transition 5s - 5s5p of In and Sr.

18 pages, 7 tables

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