Imaging of Alignment, Deformation and Dissociation of CS2 Molecules using Ultrafast Electron Diffraction

Abstract

Imaging the structure of molecules in transient excited states remains a challenge due to the extreme requirements for spatial and temporal resolution. Ultrafast electron diffraction from aligned molecules (UEDAM) provides atomic resolution and allows for the retrieval of structural information without the need to rely on theoretical models. Here we use UEDAM and femtosecond laser mass spectrometry (FLMS) to investigate the dynamics in carbon disulfide (CS2) following the interaction with an intense femtosecond laser pulse. We have retrieved images of ground state and excited molecules with 0.03 Å precision. We have observed that the degree of alignment reaches an upper limit at laser intensities below the ionization threshold, and found evidence of structural deformation, dissociation, and ionization at higher laser intensities.

References in corpus (2)

• X-ray diffraction from isolated and strongly aligned gas-phase molecules with a free-electron laser
• \emph{In situ} measurement of three-dimensional ion densities in focused femtosecond pulses

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• Robust inversion of time-resolved data via forward-optimisation in a trajectory basis
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• Ultrafast Electron Diffraction: Visualizing Dynamic States of Matter