Impact of single-particle compressibility on the fluid-solid phase transition for ionic microgel suspensions

Abstract

We study ionic microgel suspensions composed of swollen particles for various single-particle stiffnesses. We measure the osmotic pressure $\pi$ of these suspensions and show that it is dominated by the contribution of free ions in solution. As this ionic osmotic pressure depends on the volume fraction of the suspension $\varphi$, we can determine $\varphi$ from $\pi$, even at volume fractions so high that the microgel particles are compressed. We find that the width of the fluid-solid phase coexistence, measured using $\varphi$, is larger than its hard-sphere value for the stiffer microgels that we study and progressively decreases for softer microgels. For sufficiently soft microgels, the suspensions are fluid-like, irrespective of volume fraction. By calculating the dependence on $\varphi$ of the mean volume of a microgel particle, we show that the behavior of the phase-coexistence width correlates with whether or not the microgel particles are compressed at the volume fractions corresponding to fluid-solid coexistence.

5 pages, 3 figures

References in corpus (1)

• Phase diagram of Hertzian spheres

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