paper

Effect of yttrium substitution on the superconducting properties of the system LaYOFBiS

arXiv:1410.0084 · doi:10.1103/PhysRevB.90.054510

Abstract

We present the effect of yttrium substitution on superconductivity in the LaYOFBiS system. Polycrystalline samples with nominal Y concentrations up to 40% were synthesized and characterized via electrical resistivity, magnetic susceptibility, and specific heat measurements. Y substitution reduces the lattice parameter \textit{a} and unit cell volume \textit{V}, and a correlation between the lattice parameter \textit{c}, the La-O-La bond angle, and the superconducting critical temperature is observed. The chemical pressure induced by Y substitution for La produces neither the high- superconducting phase nor the structural phase transition seen in LaOFBiS under externally applied pressure.

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