Thermodynamics and dynamics of the inherent states at the glass transition
arXiv:1408.5767 · doi:10.1016/j.jnoncrysol.2014.08.025
Abstract
It has been recently shown that one can understand the Prigogine-Defay ratio at the glass transition in terms of freezing into one of the many inherent states of the undercooled liquid. In the present paper, the treatment is extended to the dynamics at the glass transition to show the connection to isomorphism and density scaling. In addition, the energy limits for stable inherent states are discussed.
paper accepted for Proceedings IDMRCS 2013 in Barcelona, special issue of Journal of Non-Crystalline Solids
References in corpus (5)
- Supercooled Liquids for Pedestrians
- Pressure-energy correlations in liquids. I. Results from computer simulations
- Determination of the Thermodynamic Scaling Exponent from Static, Ambient-Pressure Quantities
- Single-order-parameter description of glass-forming liquids: A one-frequency test
- Statistical mechanics of Roskilde liquids: Configurational adiabats, specific heat contours and density dependence of the scaling exponent
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