Crystal growth and annealing study of fragile, non-bulk superconductivity in YFe${}_2$Ge${}_2$

Abstract

We investigated the occurrence and nature of superconductivity in single crystals of YFe${}_2$Ge${}_2$ grown out of Sn flux by employing x-ray diffraction, electrical resistivity, and specific heat measurements. We found that the residual resistivity ratio (RRR) of single crystals can be greatly improved, reaching as high as $\sim$60, by decanting the crystals from the molten Sn at $\sim$350${}^{\circ }$C and/or by annealing at temperatures between 550${}^{\circ }$C and 600${}^{\circ }$C. We found that samples with RRR $\gtrsim$ 34 showed resistive signatures of superconductivity with the onset of the superconducting transition $T_c\approx 1.4$ K. RRR values vary between 35 and 65 with, on average, no systematic change in $T_c$ value, indicating that systematic changes in RRR do not lead to comparable changes in $T_c$. Specific heat measurements on samples that showed clear resistive signatures of a superconducting transition did not show any signature of a superconducting phase transition, which suggests that the superconductivity observed in this compound is either some sort of filamentary, strain stabilized superconductivity associated with small amounts of stressed YFe${}_2$Ge${}_2$ (perhaps at twin boundaries or dislocations) or is a second crystallographic phase present at levels below detection capability of conventional powder x-ray techniques.

arXiv comment8 pages, 11 figures

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• Anisotropic magnetization, specific heat and resistivity of RFe2Ge2 single crystals
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• Unconventional bulk superconductivity in YFe${}_2$Ge${}_2$ single crystals
• Coexistence of ferromagnetic and stripe-type antiferromagnetic spin fluctuations in YFe${}_2$Ge${}_2$
• Composition dependence of bulk superconductivity in YFe2Ge2
• Fermi surface and mass renormalization in the iron-based superconductor YFe${}_2$Ge${}_2$
• Nearly ferromagnetic metal state in the collapsed tetragonal phase of YFe${}_2$(Ge,Si)${}_2$
• On magnetic structure of CuFe2Ge2: constrains from the 57Fe Mossbauer spectroscopy
• Intrinsic defect intolerance in the ultra-pure metal PtSn${}_4$