55~Tesla coercive magnetic field in frustrated Sr${}_3$NiIrO${}_6$

Abstract

We have measured extremely large coercive magnetic fields of up to 55~T in Sr${}_3$NiIrO${}_6$, with a switched magnetic moment $\approx 0.8{\mu }_{\mathrm{B}}$ per formula unit. As far as we are aware, this is the largest coercive field observed thus far. This extraordinarily hard magnetism has a completely different origin from that found in conventional ferromagnets. Instead, it is due to the evolution of a frustrated antiferromagnetic state in the presence of strong magnetocrystalline anisotropy due to the overlap of spatially-extended Ir${}^{4+}$ 5$d$ orbitals with oxygen 2$p$ and Ni${}^{2+}$ 3$d$ orbitals. This work highlights the unusual physics that can result from combining the extended $5d$ orbitals in Ir${}^{4+}$ with the frustrated behaviour of triangular lattice antiferromagnets.