Photoionization of bonding and antibonding-type atom-fullerene hybrid states in Cd@C${}_{60}$ vs Zn@C${}_{60}$60

Abstract

Powerful hybridization of the Cd 4$d$ state with the $d$-angular momentum state of C${}_{60}$ $\pi$ symmetry is found in the local density approximation (LDA) structure of Cd@C${}_{60}$ ground state. The photoionization of the resulting symmetric and antisymmetric levels are computed using the time dependent LDA method to include electron correlations. Cross sections exhibit effects of the C${}_{60}$ plasmonic motion coherently coupled to the diffraction-type cavity oscillations induced by local emissions from C${}_{60}$. The Cd@C${}_{60}$ results exhibit a substantial difference from our previous results for Zn@C${}_{60}$.

6 pages, 4 figures, Submitted to J. Phys. B

References in corpus (2)

• Exact solvability of the quantum Rabi models within Bogoliubov operators
• Room Temperature Electrical Detection of Spin Coherence in C60

Cited by in corpus (5)

• Effects of exchange-correlation potentials on the density functional description of C_60 versus C_240 photoionization
• Coherence of Auger and inter-Coulombic decay processes in the photoionization of Ar@C60 versus Kr@C60
• Photoemission from hybrid states of Cl@$C_{60}$ before and after a stabilizing charge transfer
• A density functional theory based comparative study of hybrid photoemissions from Cl@C60, Br@C60 and I@C60
• Electron vacancy-level dependent hybrid photoionization of F-@C60+ molecule