Influence of disorder on the structural phase transition and magnetic interactions in Ba${}_{3-x}$Sr${}_x$Cr${}_2$O${}_8$

Abstract

The spin dimer system ${\mathrm{Ba}}_{3-x}{\mathrm{Sr}}_x\mathrm{C}{\mathrm{r}}_2{\mathrm{O}}_8$ is a solid solution of the triplon Bose-Einstein condensation candidates $\mathrm{B}{\mathrm{a}}_3\mathrm{C}{\mathrm{r}}_2{\mathrm{O}}_8$ and $\mathrm{S}{\mathrm{r}}_3\mathrm{C}{\mathrm{r}}_2{\mathrm{O}}_8$. The magnetic intradimer interaction constant $J_0$ in this spin system can be tuned by varying the Sr content $x$. Very interestingly, this variation of $J_0$ with $x$ is highly nonlinear. In the present study, we show that this peculiar behavior of $J_0$ can be only partly explained by the changes in the average crystal structure alone. We report on neutron powder diffraction experiments to probe the corresponding structural details. Performing extended Hückel tight binding calculations based on those structural details obtained at liquid helium temperatures, we found that the change of the magnetic interaction constant can be well reproduced by taking into account the presence of a structural transition due to the Jahn-Teller active Cr${}^{5+}$-ions. This transition, lifting the orbital degeneracy and thereby the magnetic frustration in the system, is heavily influenced by disorder in the system arising from partially exchanging Ba with Sr.

References in corpus (2)

• Bose-Einstein Condensation of Triplons in Ba3Cr2O8
• Weakly coupled $s=1/2$ quantum spin singlets in Ba${}_3$Cr${}_2$O${}_8$

Cited by in corpus (2)

• Tuning magnetic spirals beyond room temperature with chemical disorder
• Single crystal growth and study of the magnetic properties of the mixed spin-dimer system Ba${}_{3-x}$Sr${}_x$Cr${}_2$O${}_8$