paper

Spontaneous growth of diamond from MnNi solvent-catalyst using opposed anvil-type high-pressure apparatus

arXiv:1404.3618 · doi:10.1016/j.jcrysgro.2014.03.002

Abstract

In this paper an overview of the application of opposed anvil-type high-pressure high-temperature apparatus for spontaneous growth of diamond crystals by solvent-catalyst technique is presented. The process makes use of a molten Mn47Ni53 catalyst to initiate the graphite-diamond transformation reaction. The pressure and temperature requirements to obtain reproducible spontaneous diamond crystallization were around 52.5-54 kbar and 1270-1320 C. The crystals had well-shaped cubo-structured morphology with the 100 and 111 faces and grain sizes of 0.2-0.5 mm. This work can stimulate future experimental exploration of spontaneous diamond crystallization by using other solvent-catalyst metals.

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