Superconductivity of LaCoSn and LaRhSn: A comparative study
arXiv:1403.6030 · doi:10.1103/PhysRevB.89.125111
Abstract
We report the electric transport and thermodynamic properties of the skutterudite-related LaCoSn and LaRhSn superconductors. Applying an external pressure to LaRhSn, the resistive superconducting critical temperature Tc decreases, while the critical temperature of LaCoSn is enhanced with increasing pressure. The positive pressure coefficient dTc/dP correlates with a subtle structural transition in LaCoSn and is discussed in the context of lattice instabilities. Specific-heat data show that both compounds are typical BCS superconductors. However, LaRhSn also exhibits a second superconducting phase at higher temperatures, which is characteristic of inhomogeneous superconductors. We calculate the specific heat for an inhomogeneous superconducting phase, which agrees well with experimental C(T) data for LaRhSn. We also found that an applied pressure reduces this second superconducting phase.
8 pages, 10 figures, revtex