On the Virial Series for a Gas of Particles with Uniformly Repulsive Pairwise Interaction
arXiv:1403.1621
Abstract
The pressure of a gas of particles with a uniformly repulsive pair interaction in a finite container is shown to satisfy (exactly as a formal object) a "viscous" Hamilton-Jacobi (H-J) equation whose solution in power series is recursively given by the variation of constants formula. We investigate the solution of the H-J and of its Legendre transform equation by the Cauchy-Majorant method and provide a lower bound to the radius of convergence on the virial series of the gas which goes beyond the threshold established by Lagrange's inversion formula. A comparison between the behavior of the Mayer and virial coefficients for different regimes of repulsion intensity is also provided.
Preliminary version; 62 pages, 9 figures