On the structure of the Nx phase of symmetric dimers

Abstract

NMR measurements on a selectively deuteriated liquid crystal dimer CB-C9-CB exhibiting two nematic phases show that the molecules in the lower temperature nematic phase, Nx, experience a chiral environment and are ordered about a unique direction. The results are contrasted with previous reports that proposed a twist-bend spatial variation of the director. A structural model is proposed wherein the molecules show organization into highly correlated assemblies of opposite chirality.

12 pages, 3 Figures, Supporting information included in the same pdf (updated in v2, 11 pages)