Critical Missing Equation of Quantum Physics for Understanding Atomic Structures
arXiv:1311.0237
Abstract
This paper presents an optimization approach to explain why and how a quantum system evolves from an arbitrary initial state to a stationary state, satisfying the time-independent Schrödinger equation. It also points out the inaccuracy of this equation, which is critial important in quantum mechanics and quantum chemistry, due to a fundamental flaw in it conflicting with the physical reality. The some directions are suggested on how to modify the equation to fix the problem
Presented in the 12th international conference on Mathematical Results in Quantum Mechanics (QMATH12), Humboldt University of Berlin, September, 2013