Antinematic local order in dendrimer liquids

Abstract

We use monomer-resolved numerical simulations to study the positional and orientational structure of a dense dendrimer solution, focusing on the effects of dendrimers' prolate shape and deformability on the short-range order. Our results provide unambiguous evidence that the nearest-neighbor shell of a tagged particle consists of a mixture of crossed, side-by-side, side-to-end, and end-to-end pair configurations, imposing antinematic rather than nematic order observed in undeformable rodlike particles. This packing pattern persists even at densities where particle overlap becomes sizable. We demonstrate that the antinematic arrangement is compatible with the A15 crystal lattice reported in several dendrimer compounds.

6 pages, 3 figures

References in corpus (4)

• Phase diagram of Hertzian spheres
• Computer Assembly of Cluster-Forming Amphiphilic Dendrimers
• Novel crystal phase in suspensions of hard ellipsoids
• Phase diagram of Gaussian-core nematics

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