Nanoscopic friction under electrochemical control
arXiv:1309.6658 · doi:10.1103/PhysRevLett.112.055502
Abstract
We propose a theoretical model of friction under electrochemical conditions focusing on the interaction of a force microscope tip with adsorbed polar molecules of which the orientation depends on the applied electric field. We demonstrate that the dependence of friction force on the electric field is determined by the interplay of two channels of energy dissipation: (i) the rotation of dipoles and (ii) slips of the tip over potential barriers. We suggest a promising strategy to achieve a strong dependence of nanoscopic friction on the external field based on the competition between long range electrostatic interactions and short range chemical interactions between tip and adsorbed polar molecules.
5 pages, 5 figures
References in corpus (1)
Cited by in corpus (4)
- Electric-field frictional effects in confined zwitterionic molecules
- Tuning friction at material-nanoparticle-liquid interfaces with an external electric field
- Friction on incommensurate substrates: Role of anharmonicity and defects
- Electrotunable friction with ionic liquid lubricants: how important is the molecular structure of the ions?