Time-dependent renormalized natural orbital theory applied to the two-electron spin-singlet case: ground state, linear response, and autoionization

Abstract

Favorably scaling numerical time-dependent many-electron techniques such as time-dependent density functional theory (TDDFT) with adiabatic exchange-correlation potentials typically fail in capturing highly correlated electron dynamics. We propose a method based on natural orbitals, i.e., the eigenfunctions of the one-body reduced density matrix, that is almost as inexpensive numerically as adiabatic TDDFT, but which is capable of describing correlated phenomena such as doubly excited states, autoionization, Fano profiles in the photoelectron spectra, and strong-field ionization in general. Equations of motion (EOM) for natural orbitals and their occupation numbers have been derived earlier. We show that by using renormalized natural orbitals (RNO) both can be combined into one equation governed by a hermitian effective Hamiltonian. We specialize on the two-electron spin-singlet system, known as being a "worst case" testing ground for TDDFT, and employ the widely used, numerically exactly solvable, one-dimensional helium model atom (in a laser field) to benchmark our approach. The solution of the full, nonlinear EOM for the RNO is plagued by instabilities, and resorting to linear response is not an option for the ultimate goal to study nonperturbative dynamics in intense laser fields. We therefore make two rather bold approximations: we employ the initial-state-"frozen" effective RNO Hamiltonian for the time-propagation and truncate the number of RNO to only two per spin. Surprisingly, it turns out that even with these strong approximations we obtain a highly accurate ground state, reproduce doubly-excited states, and autoionization.

REVTeX, 16 pages, 8 figures

References in corpus (4)

• Pinning of Fermionic Occupation Numbers
• Adiabatic Approximation of the Correlation Function in the Density-Functional Treatment of Ionization Processes
• Momentum distributions in time-dependent density functional theory: Product phase approximation for non-sequential double ionization in strong laser fields
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Cited by in corpus (11)

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• One-body reduced density-matrix functional theory in finite basis sets at elevated temperatures
• Equations of motion for natural orbitals of strongly driven two-electron systems
• Nonsequential double ionization with time-dependent renormalized-natural-orbital theory
• Strong-field absorption and emission of radiation in two-electron systems calculated with time-dependent natural orbitals
• The BBGKY hierarchy for ultracold bosonic systems: II. Applications
• Time-dependent renormalized-natural-orbital theory applied to laser-driven H${}_2^{+}$
• Dynamics of Local Symmetry Correlators for Interacting Many-Particle Systems
• Density-Matrix Propagation Driven by Semiclassical Correlation
• Multi-electron dynamics in the tunnel ionization of correlated quantum systems
• Single-photon double ionization: renormalized-natural-orbital theory vs multi-configurational Hartree-Fock