Quantum-kinetic theory of steady-state photocurrent generation in thin films: Coherent versus incoherent coupling

Abstract

The generation of photocurrents due to coupling of electrons to both classical and quantized electromagnetic fields in thin semiconductor films is described within the framework of the nonequilibrium Green's function formalism. For the coherent coupling to classical fields corresponding to single field operator averages, an effective two-time intraband self-energy is derived from a band decoupling procedure. The evaluation of coherent photogeneration is performed self-consistently with the propagation of the fields by using for the latter a transfer matrix formalism with an extinction coefficient derived from the electronic Green's functions. For the "incoherent" coupling to fluctuations of the quantized fields, which need to be considered for the inclusion of spontaneous emission, the first self-consistent Born self-energy is used, with full spatial resolution in the photon Green's functions. These are obtained from the numerical solution of Dyson and Keldysh equations including a nonlocal photon self-energy based on the same interband polarization function as used for the coherent case. A comparison of the spectral and integral photocurrent generation pattern reveals a close agreement between coherent and incoherent coupling for the case of an ultrathin, selectively contacted absorber layer at short circuit conditions.

11 pages, 7 figures, published version

References in corpus (6)

• Theory and simulation of quantum photovoltaic devices based on the non-equilibrium Green's function formalism
• Quantum-kinetic theory of photocurrent generation via direct and phonon-mediated optical transitions
• Theory and simulation of photogeneration and transport in Si-SiOx superlattice absorbers
• Simulation of nanostructure-based high-efficiency solar cells: challenges, existing approaches and future directions
• Effective microscopic theory of quantum dot superlattice solar cells
• Efficiency of thin film photocells

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