Geometric phase effects in dynamics near conical intersections: Symmetry breaking and spatial localization
arXiv:1306.6387 · doi:10.1103/PhysRevLett.111.220406
Abstract
We show that finite systems with conical intersections can exhibit spontaneous symmetry breaking which manifests itself in spatial localization of eigenstates. This localization has a geometric phase origin and is robust against variation of model parameters. The transition between localized and delocalized eigenstate regimes resembles a continuous phase transition. The localization slows down the low-energy quantum nuclear dynamics at zero and low temperatures.
5 pages, 5 figures
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