Theory of Nucleation in Phase-separating Nanoparticles

Abstract

The basic physics of nucleation in solid \hl{single-crystal} nanoparticles is revealed by a phase-field theory that includes surface energy, chemical reactions and coherency strain. In contrast to binary fluids, which form arbitrary contact angles at surfaces, complete "wetting" by one phase is favored at binary solid surfaces. Nucleation occurs when surface wetting becomes unstable, as the chemical energy gain (scaling with area) overcomes the elastic energy penalty (scaling with volume). The nucleation barrier thus decreases with the area-to-volume ratio and vanishes below a critical size, and nanoparticles tend to transform in order of increasing size, leaving the smallest particles homogeneous (in the phase of lowest surface energy). The model is used to simulate phase separation in realistic nanoparticle geometries for \ce{Li_XFePO4}, a popular cathode material for Li-ion batteries, and collapses disparate experimental data for the nucleation barrier, with no adjustable parameters. Beyond energy storage, the theory generally shows how to tailor the elastic and surface properties of a solid nanostructure to achieve desired phase behavior.

7 pages, 4 figs

References in corpus (4)

• Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics
• Suppression of Phase Separation in LiFePO4 Nanoparticles During Battery Discharge
• Coherency strain and the kinetics of phase separation in LiFePO4
• Phase Field Theory of Heterogeneous Crystal Nucleation

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• Quantitative predictions of thermodynamic hysteresis: Temperature-dependent character of the phase transition in Pd-H
• Scale bridging description of coherent phase equilibria in the presence of surfaces and interfaces
• Interfacial resistive switching by multiphase polarization in ion-intercalation nanofilms