Effect of alkyl substituents on the adsorption of thienylenevinylene oligomers on the Si (100) surface
arXiv:1204.3983 · doi:10.1016/S0039-6028(00)00946-8
Abstract
The adsorption of thienylenevinylene oligomers on the Si(100) surface has been investigated using scanning tunneling microscopy. The mode of substitution of the thiophene ring exerts a strong influence on the adsorption configurations and the images of the oligomer based on 3,4-dihexyl thiophene are highly voltage dependent. We discuss the influence of the alkyl chains on the adsorption process and on the appearance of the molecules in the STM images.