Low-Energy Scale Excitations in the Spectral Function of Organic Monolayer Systems

Abstract

Using high-resolution photoemission spectroscopy we demonstrate that the electronic structure of several organic monolayer systems, in particular 1,4,5,8-naphthalene tetracarboxylic dianhydride and Copper-phtalocyanine on Ag(111), is characterized by a peculiar excitation feature right at the Fermi level. This feature displays a strong temperature dependence and is immediatly connected to the binding energy of the molecular states, determined by the coupling between the molecule and the substrate. At low temperatures, the line-width of this feature, appearing on top of the partly occupied lowest unoccupied molecular orbital of the free molecule, amounts to only $\approx 25$ meV, representing an unusually small energy scale for electronic excitations in these systems. We discuss possible origins, related e.g. to many-body excitations in the organic-metal adsorbate system, in particular a generalized Kondo scenario based on the single impurity Anderson model.

6 pages, 3 figures, accepted as PRB Rapid Communications

References in corpus (3)

• High Resolution Photoemission Study on Low-T_K Ce Systems: Kondo Resonance, Crystal Field Structures, and their Temperature Dependence
• Energy Shift and Wavefunction Overlap of Metal-Organic Interface-States
• Signature of quantum criticality in photoemission spectroscopy at elevated temperature

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• Coulomb blockade and Kondo effect in the electronic structure of Hubbard molecules connected to metallic leads: a finite-temperature exact-diagonalization study
• First-principles quantum transport simulation of CuPc on Au(111) and Ag(111)