paper

Solution of the momentum-space Schrödinger equation for bound states of the N-dimensional Coulomb problem (revisited)

arXiv:1111.1661 · doi:10.1002/andp.201100330

Abstract

The Schrödinger-Coulomb Sturmian problem in , , is considered in the momentum representation. An integral formula for the Gegenbauer polynomials, found recently by Cohl [arXiv:1105.2735], is used to separate out angular variables and reduce an integral Sturmian eigenvalue equation in to a Fredholm one on . A kernel of the latter equation contains the Legendre function of the second kind. A symmetric Poisson-type series expansion of that function into products of the Gegenbauer polynomials, established by Ossicini [Boll. Un. Mat. Ital. 7 (1952) 315], is then used to determine the Schrödinger-Coulomb Sturmian eigenvalues and associated momentum-space eigenfunctions. Finally, a relationship existing between solutions to the Sturmian problem and solutions to a (physically more interesting) energy eigenvalue problem is exploited to find the Schrödinger-Coulomb bound-state energy levels in , together with explicit representations of the associated normalized momentum-space Schrödinger-Coulomb Hamiltonian eigenfunctions.

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