Anomalous low-energy phonons in nearly tetragonal BiFeO3 thin films

Abstract

We present evidence for a concomitant structural and ferroelectric transformation around $T_S\sim 360$ K in multiferroic BiFeO${}_3$/LaAlO${}_3$ thin films close to the tetragonal phase. Phonon excitations are investigated by using Raman scattering as a function of temperature. The low-energy phonon modes at 180-260 cm${}^{-1}$ related to the FeO${}_6$ octahedron tilting show anomalous behaviors upon cooling through $T_S$; (i) a large hardening amounting to 15 cm${}^{-1}$, (ii) an increase of intensity by one order of magnitude, and (iii) an appearance of a dozen new modes. In contrast, the high-frequency modes exhibit only weak anomalies. This suggests an intimate coupling of octahedron tilting to ferroelectricity leading to a simultaneous change of structural and ferroelectric properties.

4 pages, 5figures