Experimental determination of the Weiss temperature of Mn${}_{12}$-ac and Mn${}_{12}$-ac-MeOH

Abstract

We report measurements of the susceptibility in the temperature range from $3.5$ K to $6.0$ K of a series of Mn${}_{12}$-ac and Mn${}_{12}$-ac-MeOH samples in the shape of rectangular prisms of length $l_c$ and square cross-section of side $l_a$. The susceptibility obeys a Curie-Weiss Law, $\chi =C/(T-\theta )$, where $\theta$ varies systematically with sample aspect ratio. Using published demagnetization factors, we obtain $\theta$ for an infinitely long sample corresponding to intrinsic ordering temperatures $T_c\approx 0.85$ K and $\approx 0.74$ K for Mn${}_{12}$-ac and Mn${}_{12}$-ac-MeOH, respectively. The difference in $T_c$ for two materials that have nearly identical unit cell volumes and lattice constant ratios suggests that, in addition to dipolar interactions, there is a non-dipolar (exchange) contribution to the Weiss temperature that differs in the two materials because of the difference in ligand molecules.

4.5 pages