The application of the global isomorphism to the study of liquid-vapor equilibrium in two and three dimensional Lenard-Jones fluids
arXiv:1008.2434 · doi:10.1063/1.3499857
Abstract
We analyze the interrelation between the coexistence curve of the Lennard-Jones fluid and the Ising model in two and three dimensions within the global isomorphism approach proposed earlier [V. L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)]. In case of two dimensions we use the exact Onsager result to construct the binodal of the corresponding Lennard-Jones fluid and compare it with the results of the simulations. In the three dimensional case we use available numerical results for the Ising model for the corresponding mapping. The possibility to observe the singularity of the binodal diameter is discussed.
9 pages, 2 figures
References in corpus (6)
- Asymmetric Fluid Criticality I: Scaling with Pressure Mixing
- Modeling the Searching Behavior of Social Monkeys
- Simple geometrical interpretation of the linear character for the Zeno-line and the rectilinear diameter
- Singular Coexistence-curve Diameters: Experiments and Simulations
- The nature of the rectilinear diameter singularity
- Global isomorphism between the Lenard-Jones fluids and the Ising model
Cited by in corpus (7)
- The critical compressibility factor value: associative fluids and liquid alkali metals
- The unified picture for the classical laws of Batschinski and the rectilinear diameter for molecular fluids
- The critical compressibility factor of fluids from the Global Isomorphism approach
- The Vliegenthart-Lekkerkerker relation. The case of the -fluids
- Surface tension of molecular liquids: Lattice gas approach
- Hard-core attractive Yukawa fluid global isomorphism with the lattice gas model
- The application of the global isomorphism to the surface tension of the liquid-vapor interface of the Lennard-Jones fluids