Generalization of Gibbs Entropy and Thermodynamic Relation
arXiv:1007.3684 · doi:10.1016/j.physa.2013.10.012
Abstract
In this paper, we extend Gibbs's approach of quasi-equilibrium thermodynamic processes, and calculate the microscopic expression of entropy for general non-equilibrium thermodynamic processes. Also, we analyze the formal structure of thermodynamic relation in non-equilibrium thermodynamic processes.
Typographical errors in equation (28), (29) and (30) are corrected