Direct Visualization of Two-State Dynamics on Metallic Glass Surfaces Well Below Tg

Abstract

Direct atomically resolved observation of dynamics deep in the glassy regime has proved elusive for atomic and molecular glasses. Studies below the glass transition temperature Tg are especially rare due to long waiting times required to observe dynamics. Here we directly visualize surface glass dynamics deep in the glassy regime. We analyze scanning tunneling microscopy movies of the surface of metallic glasses with time resolution as fast as 1 minute and extending up to 1,000 minutes. Rearrangements of surface cluster occur almost exclusively by two-state hopping (P(3-state) ~ 0.06). All clusters are compact structures with a width of 2-8 atomic spacings along the surface plane. The two-state dynamics is both spatially and temporally heterogeneous. We estimate an average activation free energy of 14 kBT for surface clusters.

11 pages, 4 figures

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• Direct experimental evidence of a growing length scale accompanying the glass transition
• Theory of Structural Glasses and Supercooled Liquids
• Direct observation of molecular cooperativity near the glass transition
• A universal origin for secondary relaxations in supercooled liquids and structural glasses

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