Anomalous Raman scattering from phonons and electrons of superconducting FeSe${}_{0.82}$

Abstract

We report interesting anomalies in the temperature dependent Raman spectra of FeSe${}_{0.82}$ measured from 3K to 300K in the spectral range from 60 to 1800 cm${}^{-1}$ and determine their origin using complementary first-principles density functional calculations. A phonon mode near 100 cm${}^{-1}$ exhibits a sharp increase by $\sim$ 5% in frequency below a temperature T${}_s$ ($\sim$ 100 K) attributed to strong spin-phonon coupling and onset of short-range antiferromagnetic order. In addition, two high frequency modes are observed at 1350 cm${}^{-1}$ and 1600 cm${}^{-1}$, attributed to electronic Raman scattering from ($x^2-y^2$)to $xz$ / $yz$ $d$-orbitals of Fe.

19 pages, 4 figures, 1 table

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• HHG-laser-based time- and angle-resolved photoemission spectroscopy of quantum materials
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• On the phonon dispersion relation of single-crystalline $\beta$--FeSe
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