Thioglycolic acid on the gold (111) surface and Raman vibrational spectra

Abstract

The interaction of thioglycolic acid with the Au(111) surface is investigaged, and it is found that at the low coverage the molecule lies down on the substrate. If the mercaptan-hydrogen atom is eliminated, the resulting SCH_2COOH molecule is randomly oriented on the surface. If the carboxylic acid group in the HSCH_2COOH molecule is deprotonated instead, the HSCH_2COO^ molecule lies down on the surface. However, when the mercaptan-hydrogen atom in the HSCH_2COO^- molecule is removed, the resulting SCH_2COO^- molecule rises up to a certain level on the substrate. The calculated Raman vibrational spectra decipher which compounds and atomic displacements contribute to the corresponding frequencies. We thus propose a consistent mechanism for the deposition of thioglycolic acid on the Au(111) surface.

18 pages, 5 figures, submitted to J. Chem. Phys

References in corpus (4)

• Do methanethiol adsorbates on the Au(111) surface dissociate?
• Coverage dependence of the 1-propanol adsorption on the Si(001) surface and fragmentation dynamics
• Headgroup dimerization in methanethiol monolayers on the Au(111) surface: a density functional theory study
• The CH3SH molecule deposited on Cu(111) and deprotonation