Modulation effects within the mean-field theory of electrolyte solutions

Abstract

The consequences of source charge and surface modulation are studied within the framework of the Poisson-Boltzmann theory of electrolyte solutions. Through a consideration of various examples, it is found that inherent modulation can lead to both like-charge attraction and overcharging effects.

A note has been added regarding additional references

References in corpus (3)

• Electrostatic correlations: from Plasma to Biology
• Attraction between DNA molecules mediated by multivalent ions
• Universal reduction of pressure between charged surfaces by long-wavelength surface charge modulation

Cited by in corpus (5)

• Interaction between Heterogeneously Charged Surfaces: Surface Patches and Charge Modulation
• Electrostatics of Patchy Surfaces
• Electrostatic Attraction between Overall Neutral Surfaces
• Electric double layers with surface charge modulations: Novel exact Poisson-Boltzmann solutions
• Electrostatic interactions between discrete helices of charge