Laser spectroscopy of gas confined in nanoporous materials

Abstract

We show that high-resolution laser spectroscopy can probe surface interactions of gas confined in nano-cavities of porous materials. We report on strong line broadening and unfamiliar lineshapes due to tight confinement, as well as signal enhancement due to multiple photon scattering. This new domain of laser spectroscopy constitute a challenge for the theory of collisions and spectroscopic lineshapes, and open for new ways of analyzing porous materials and processes taking place therein.

4 pages, 3 figures, partly presented orally at 7th International Conference on Tunable Diode Laser Spectroscopy (TDLS), July 2009 in Zermatt, Switzerland; Accepted for Applied Physics Letters (December 2009)