Doping dependence of the lattice dynamics in Ba(Fe${}_{1-x}$Co${}_x$)${}_2$As${}_2$ studied by Raman spectroscopy

Abstract

We report Raman scattering spectra of iron-pnictide superconductor Ba(Fe${}_{1-x}$Co${}_x$)${}_2$As${}_2$ single crystals with varying cobalt $x$ content. Upon cooling through the tetragonal-to-orthorhombic transition, we observe a large splitting of the E${}_g$ in-plane phonon modes involving Fe and As displacements. The splitting of the in-plane phonons at the transition is strongly reduced upon doping and disappears for $x=0.06$ qualitatively following the trend displayed by the Fe magnetic moment. The origin of the splitting is discussed in terms of magnetic frustration inherent to iron-pnictide systems and we argue that such enhanced splitting may be linked to strong spin-phonon coupling.

6 pages, 6 figures