Dynamical Heterogeneities and Cooperative Motion in Smectic Liquid Crystals

Abstract

Using simulations of hard rods in smectic-A states, we find non-gaussian diffusion and heterogeneous dynamics due to the equilibrium periodic smectic density profiles, which give rise to permanent barriers for layer-to-layer diffusion. This relaxation behavior is surprisingly similar to that of non-equilibrium supercooled liquids, although there the particles are trapped in transient (instead of permanent) cages. Interestingly, we also find stringlike clusters of up to 10 inter-layer rods exhibiting dynamic cooperativity in this equilibrium state.

10 pages, 4 figures