Multiple quantum NMR dynamics of spin-1/2 carrying molecules of a gas in nanopores

Abstract

We consider the multiple quantum (MQ) NMR dynamics of a gas of spin carrying molecules in nanocavities. MQ NMR dynamics is determined by the residual dipole-dipole interactions which are not averaged completely due to the molecular diffusion in nanopores. Since the averaged non-secular Hamiltonian describing MQ NMR dynamics depends on only one coupling constant, this Hamiltonian commutes with the square of the total spin angular momentum ${\hat{I}}^2$. We use the basis of common eigenstates of ${\hat{I}}^2$ and the projection of $I$ on the external magnetic field for investigation of MQ NMR dynamics. This approach allows us to study MQ NMR dynamics in systems consisting of several hundreds of spins. The analytical approximation of the stationary profile of MQ coherences is obtained. The analytical expressions for MQ NMR coherence intensities of the five-spin system in a nanopore are found. Numerical investigations allow us to find the dependencies of intensities of MQ coherences on their orders (the profiles of MQ coherences) in systems consisting of 600 spins and even more. It is shown that the stationary MQ coherence profile in the considered system is an exponential one.

8 pages, 5 figures

References in corpus (3)

• Dynamics and Control of a Quasi-1D Spin System
• Effective one-body dynamics in multiple-quantum NMR experiments
• Multiple Quantum NMR Dynamics in Dipolar Ordered Spin Systems

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• Many-particle Entanglement in Multiple Quantum NMR Spectroscopy
• The multiple quantum NMR dynamics in systems of equivalent spins with the dipolar ordered initial state
• Multiple quantum NMR dynamics in a gas of spin-carrying molecules in fluctuating nanopores
• Multiple quantum NMR of spin-carrying molecules in nanopores: high order corrections to the two-spin/two-quantum Hamiltonian
• Many-spin entanglement in multiple quantum NMR with a dipolar ordered initial state