Quantum and semiclassical spin networks: from atomic and molecular physics to quantum computing and gravity

Abstract

The mathematical apparatus of quantum--mechanical angular momentum (re)coupling, developed originally to describe spectroscopic phenomena in atomic, molecular, optical and nuclear physics, is embedded in modern algebraic settings which emphasize the underlying combinational aspects. SU(2) recoupling theory, involving Wigner's 3nj symbols, as well as the related problems of their calculations, general properties, asymptotic limits for large entries, play nowadays a prominent role also in quantum gravity and quantum computing applications. We refer to the ingredients of this theory -and of its extension to other Lie and quantum group- by using the collective term of `spin networks'. Recent progress is recorded about the already established connections with the mathematical theory of discrete orthogonal polynomials (the so-called Askey Scheme), providing powerful tools based on asymptotic expansions, which correspond on the physical side to various levels of semi-classical limits. These results are useful not only in theoretical molecular physics but also in motivating algorithms for the computationally demanding problems of molecular dynamics and chemical reaction theory, where large angular momenta are typically involved. As for quantum chemistry, applications of these techniques include selection and classification of complete orthogonal basis sets in atomic and molecular problems, either in configuration space (Sturmian orbitals) or in momentum space. In this paper we list and discuss some aspects of these developments -such as for instance the hyperquantization algorithm- as well as a few applications to quantum gravity and topology, thus providing evidence of a unifying background structure.

References in corpus (5)

• Computing Spin Networks
• Semiclassical analysis of Wigner $3j$-symbol
• Quantum geometry and quantum algorithms
• Quantum Knitting
• Coupling of quantum angular momenta: an insight into analogic/discrete and local/global models of computation

Cited by in corpus (10)

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• 3nj Morphogenesis and Semiclassical Disentangling
• Nuclear Excitation by Electron Capture in Excited Ions
• Duality between Spin networks and the 2D Ising model
• The Screen representation of spin networks: 2D recurrence, eigenvalue equation for 6j symbols, geometric interpretation and Hamiltonian dynamics
• The Screen representation of spin networks. Images of 6j symbols and semiclassical features
• A New Recursion Relation for the 6j-Symbol
• Computing the graph-changing dynamics of loop quantum gravity