Electric dipole rovibrational transitions in HD molecule
arXiv:0809.3736 · doi:10.1103/PhysRevA.78.052503
Abstract
The rovibrational electric dipole transitions in the ground electronic state of the HD molecule are studied. A simple, yet rigorous formula is derived for the transition rates in terms of the electric dipole moment function , which is calculated in a wide range of . Our numerical results for transition rates are in moderate agreement with experiments and previous calculations, but are at least an order of magnitude more accurate.
7 pages, 1 figure