Rearrangement of Sodium ordering and its effect on physical properties in $N{a}_{x}Co{O}_2$ system

Abstract

We systematically study Raman spectroscopy of cleaved Na${}_x$CoO${}_2$ single crystals with 0.37 $\le$ x $\le$ 0.80. The Raman shift of A${}_{1g}$ mode is found to be linearly dependent on Na content, while the Raman shift of E${}_{1g}$ mode has an abnormal shift to high frequency around x = 0.5. The abnormal shift is ascribed to the occurrence of Na rearrangement in O1 structure. Temperature dependent Raman spectrum for x = 0.56 sample shows that Na rearrangement transition from O1 structure to H1 structure occurs around 240 K. Electronic transport and susceptibility for the sample with $x=0.56$ show a response to the Na rearrangement transition from O1 to H1 structure, and that different Na ordering pattern causes distinct physical properties. These results give a direct evidence to proved Na ordering effect on physical properties of Co-O plane.

arXiv comment5 pages, 6 figures

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Cited by in corpus (4)

• Transition from a phase-segregated state to single-phase incommensurate sodium ordering in Na_xCoO_2 with x \approx 0.53
• Doping effects on charge density instability in non-centrosymmetric PbxTaSe2
• Enhanced low energy fluctuations and increasing out-of-plane coherence in vacancy ordered NaxCoO2
• Temperature-driven sodium-ion dynamical-to-static crossover in the zig-zag ordered phase of Na${}_{0.5}$CoO${}_2$