A Ni-based Superconductor: the Heusler Compound ZrNi${}_2$Ga

Abstract

This work reports on the novel Heusler superconductor ZrNi2Ga. Compared to other nickel-based superconductors with Heusler structure, ZrNi2Ga exhibits a relatively high superconducting transition temperature of Tc=2.9 K and an upper critical field of 1.5 T. Electronic structure calculations show that this relatively high transition temperature is caused by a van Hove singularity, which leads to an enhanced density of states at the Fermi energy. The van Hove singularity originates from a higher order valence instability at the L-point in the electronic structure. The enhanced density of states at the Fermi level was confirmed by specific heat and susceptibility measurements. Although many Heusler compounds are ferromagnetic, our measurements of ZrNi2Ga indicate a paramagnetic state above Tc and could not reveal any traces of magnetic order down to temperatures of at least 0.35 K. We investigated in detail the superconducting state with specific heat, magnetization, and resistivity measurements. The resulting data show the typical behavior of a conventional, weakly coupled BCS (s-wave) superconductor.

27 pages in preprint style, 11 Figures

References in corpus (3)

• Calculated electronic and magnetic properties of the half-metallic, transition metal based Heusler compounds
• Anomalous vibrational effects in non-magnetic and magnetic Heusler alloys
• A critical discussion of calculated modulated structures, Fermi surface nesting and phonon softening in magnetic shape memory alloys Ni${}_2$Mn(Ga, Ge, Al) and Co${}_2$Mn(Ga, Ge)

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• Electronic fine structure in the nickel carbide superconductor Th${}_2$NiC${}_2$
• Structural and electronic properties of superconducting Heusler alloy Ni${}_2$Nb${}_{1+x}$Sn${}_{1-x}$: \textit{Ab initio} approach