Decrease of Entropy and Chemical Reactions

Abstract

The chemical reactions are very complex, and include oscillation, condensation, catalyst and self-organization, etc. In these case changes of entropy may increase or decrease. The second law of thermodynamics is based on an isolated system and statistical independence. If fluctuations magnified due to internal interactions exist in the system, entropy will decrease possibly. In chemical reactions there are various internal interactions, so that some ordering processes with decrease of entropy are possible on an isolated system. For example, a simplifying Fokker-Planck equation is solved, and the hysteresis as limit cycle is discussed.

8 pages

References in corpus (1)

• Query on Negative Temperature, Internal Interactions and Decrease of Entropy

Cited by in corpus (4)

• Decrease of Entropy, Quantum Statistics and Possible Violation of Pauli Exclusion Principle
• Quantitative Calculations of Decrease of Entropy in Thermodynamics of Microstructure and Sufficient-Necessary Condition of Decrease of Entropy in Isolated System
• Nonlinear Quantum Theory, Development of the Superposition Principle and Possible Tests
• Moderate Degree of Input Negative Entropy Flow and Decrease of Entropy in Astrophysics, Biology, Psychology and Social Systems