Vibrational spectroscopy of H2+: hyperfine structure of two-photon transitions

Abstract

We present the computation of two-photon transition spectra between ro-vibrational states of the H2+ molecular ion, including the effects of hyperfine structure and excitation polarization. The reduced two-photon matrix elements are obtained by means of a variational method. We discuss the implications of our results for high-resolution spectroscopy of H2+.

References in corpus (3)

• Relativistic corrections of mα^6 order to the ro-vibrational spectrum of H_2^+ and HD^+ molecular ions
• Narrow-line phase-locked quantum cascade laser in the 9.2 micron range
• Vibrational spectroscopy of H2+: precise evaluation of the Zeeman effect

Cited by in corpus (16)

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• Relativistic corrections of mα^6(m/M) order to the hyperfine structure of the H_2^+ molecular ion
• Two-photon spectroscopy of trapped HD${}^{+}$ ions in the Lamb-Dicke regime
• Robust, frequency-stable and accurate mid-IR laser spectrometer based on frequency comb metrology of quantum cascade lasers up-converted in orientation-patterned GaAs
• Vibrational spectroscopy of H2+: precise evaluation of the Zeeman effect
• Hyperfine structure in the H${}_2^{+}$ and HD${}^{+}$ molecular ions at $m{\alpha }^6$ order
• Precision spectroscopy of the hydrogen molecular ions HD${}^{+}$
• Laser-stimulated electric quadrupole transitions in the molecular hydrogen ion H2+
• Canceling spin-dependent contributions and systematic shifts in precision spectroscopy of the molecular hydrogen ions
• Proposal for the determination of nuclear masses by high-precision spectroscopy of Rydberg states
• Stark quenching of rovibrational states of H2+ due to motion in a magnetic field
• Quantum control of a single ${\mathrm{H}}_2^{+}$ molecular ion
• Faraday optical isolator in the 9.2 $\mu$m range for QCL applications