A selector for structural isomers of neutral molecules

Abstract

We have selected and spatially separated the two conformers of 3-aminophenol (C${}_6$H${}_7$NO) present in a molecular beam. Analogous to the separation of ions based on their mass-to-charge ratios in a quadrupole mass filter, the neutral conformers are separated based on their different mass-to-dipole-moment ratios in an ac electric quadrupole selector. For a given ac frequency, the individual conformers experience different focusing forces, resulting in different transmissions through the selector. These experiments demonstrate that conformer-selected samples of large molecules can be prepared, offering new possibilities for the study of gas-phase biomolecules.

4 pages, 4 figures (Revtex)

References in corpus (1)

• Alternating gradient focusing and deceleration of large molecules

Cited by in corpus (6)

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• Stark deceleration of OH radicals in low-field-seeking and high-field-seeking quantum states
• Manipulating the motion of large neutral molecules
• Nonlinear dynamics in an alternating gradient guide for neutral particles