Accurate long-range coefficients for two excited like isotope He atoms: He($2^{1}P$)--He($2^{1}P$), He($2^{1}P$)--He($2^{3}P$), and He($2^{3}P$)--He($2^{3}P$)

Abstract

A general formalism is used to express the long-range potential energies in inverse powers of the separation distance between two like atomic or molecular systems with $P$ symmetries. The long-range molecular interaction coefficients are calculated for the molecular symmetries $\Delta$, $\Pi$, and $\Sigma$, arising from the following interactions: He($2^{1}P$)--He($2^{1}P$), He($2^{1}P$)--He($2^{3}P$), and He($2^{3}P$)--He($2^{3}P$). The electric quadrupole-quadrupole term, $C_5$, the van der Waals (dispersion) term $C_6$, and higher-order terms, $C_8$, and $C_{10}$, are calculated \textit{ab initio} using accurate variational wave functions in Hylleraas coordinates with finite nuclear mass effects. A comparison is made with previously published results where available.

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Cited by in corpus (1)

• Theory and applications of atomic and ionic polarizabilities