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4 papers · 1 filter
Diffuse-Charge Effects on the Transient Response of Electrochemical Cells
M. van Soestbergen, P. M. Biesheuvel, M. Z. Bazant
We present theoretical models for the time-dependent voltage of an electrochemical cell in response to a current step, including effects of diffuse charge (or "space charge") near…
Nonlinear Dynamics of Capacitive Charging and Desalination by Porous Electrodes
P. M. Biesheuvel, M. Z. Bazant
The rapid and efficient exchange of ions between porous electrodes and aqueous solutions is important in many applications, such as electrical energy storage by super-capacitors, w…
Mechanical unfolding of a homopolymer globule studied by self-consistent field modelling
Alexey A. Polotsky, Marat I. Charlaganov, Frans A. M. Leermakers +3
We present results of numerical self-consistent field (SCF) calculations for the equilibrium mechanical unfolding of a globule formed by a single flexible polymer chain collapsed i…
Molecular electronics at Metal / Semiconductor Junctions Si inversion by Sub-nm Molecular Films
Omer Yaffe, Luc Scheres, Sreenivasa Reddy Puniredd +8
Electronic transport across n-Si-alkyl monolayer/Hg junctions is, at reverse and low forward bias, independent of alkyl chain-length from 18 down to 1 or 2 carbons! This and furthe…