most citedA mapping approach to surface hopping

94 citations

20 papers

physics.atom-ph2023★ 8 cited

Relation Between Photoionisation Cross Sections and Attosecond Time Delays

Jia-Bao Ji, Anatoli S. Kheifets, Meng Han +2

Determination and interpretation of Wigner-like photoionisation delays is one of the most active fields of attosecond science. Previous results have suggested that large photoionis…

physics.chem-ph2022★ 94 cited

A mapping approach to surface hopping

Jonathan R. Mannouch, Jeremy O. Richardson

We present a nonadiabatic classical-trajectory approach that offers the best of both worlds between fewest-switches surface hopping (FSSH) and quasiclassical mapping dynamics. This…

physics.chem-ph2022★ 17 cited

On detailed balance in nonadiabatic dynamics: From spin spheres to equilibrium ellipsoids

Graziano Amati, Johan E. Runeson, Jeremy O. Richardson

Trajectory-based methods that propagate classical nuclei on multiple quantum electronic states are often used to simulate nonadiabatic processes in the condensed phase. A long-stan…

physics.chem-ph2022★ 22 cited

Concentration-Flux-Steered Mechanism Exploration with an Organocatalysis Application

Moritz Bensberg, Markus Reiher

Investigating a reactive chemical system with automated reaction network exploration algorithms provides a more detailed picture of its chemical mechanism than what would be access…

physics.chem-ph2022★ 31 cited

Corresponding Active Orbital Spaces along Chemical Reaction Paths

Moritz Bensberg, Markus Reiher

The accuracy of reaction energy profiles calculated with multi-configurational electronic structure methods and corrected by multi-reference perturbation theory depends crucially o…

physics.chem-ph2022★ 26 cited

High-throughput ab initio reaction mechanism exploration in the cloud with automated multi-reference validation

Jan P. Unsleber, Hongbin Liu, Leopold Talirz +10

Quantum chemical calculations on atomistic systems have evolved into a standard approach to study molecular matter. These calculations often involve a significant amount of manual…