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20132026
most citedSinglet Oxygen Generation as a Major Cause for Parasitic Reactions during Cycling of Aprotic Lithium-Oxygen Batteries

443 citations

Showing 2017Show all

5 papers · 1 filter

cond-mat.mtrl-sci2017★ 387 cited

Biredox ionic liquids with solid-like redox density in the liquid state for high-energy supercapacitors

Eléonore Mourad, Laura Coustan, Pierre Lannelongue +6

Kinetics of electrochemical reactions are several orders of magnitude slower in solids than in liquids as a result of the much lower ion diffusivity. Yet, the solid state maximizes…

cond-mat.mtrl-sci2017★ 443 cited

Singlet Oxygen Generation as a Major Cause for Parasitic Reactions during Cycling of Aprotic Lithium-Oxygen Batteries

Nika Mahne, Bettina Schafzahl, Christian Leypold +10

Non-aqueous metal-oxygen batteries depend critically on the reversible formation/decomposition of metal oxides on cycling. Irreversible parasitic reactions cause poor rechargeabili…

cond-mat.mtrl-sci2017★ 92 cited

Capacitance of Nanoporous Carbon-Based Supercapacitors is a Trade-Off Between the Concentration and the Separability of the Ions

Ryan Burt, Konrad Breitsprecher, Barbara Daffos +6

Nanoporous carbon-based supercapacitors store electricity through adsorption of ions from the electrolyte at the surface of the electrodes. Room temperature ionic liquids, which sh…

cond-mat.mtrl-sci2017★ 34 cited

Confinement Effects on an Electron Transfer Reaction in Nanoporous Carbon Electrodes

Zhujie Li, Guillaume Jeanmairet, Trinidad Méndez-Morales +3

Nanoconfinement generally leads to drastic effect on the physical and chemical properties of ionic liquids. Here we investigate how the electrochemical reactivity in such media may…

physics.comp-ph2017★ 12 cited

Transient hydrodynamic finite size effects in simulations under periodic boundary conditions

Adelchi J. Asta, Maximilien Levesque, Rodolphe Vuilleumier +1

We use Lattice-Boltzmann and analytical calculations to investigate transient hydrodynamic finite size effects induced by the use of periodic boundary conditions in simulations at…