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q-bio.BM2014

Raman-assisted crystallography reveals end-on peroxide intermediates in a nonheme iron enzyme

Gergely Katona, Philippe Carpentier, Vincent Nivière +5

Iron-peroxide intermediates are central in the reaction cycle of many iron-containing biomolecules. We trapped iron(III)-(hydro)peroxo species in crystals of superoxide reductase (…