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9 papers · 1 filter
Transferability of crystal-field parameters for rare-earth ions in YSiO tested by Zeeman spectroscopy
Nicholas L. Jobbitt, Simon J. Patchett, Yashar Alizadeh +6
Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two point-group sites in Er:YSiO may be transferre…
Nanoscale Intergranular Corrosion and Relation With Grain Boundary Character as Studied In Situ on Copper
Mohamed Bettayeb, Vincent Maurice, Lorena H. Klein +3
The initiation of intergranular corrosion at various types of grain boundaries (GBs) was studied at the nanometer scale on microcrystalline copper in 1 mM HCl aqueous solution. In…
Extending Phenomenological Crystal-Field Methods to Point-Group Symmetry: Characterization of the Optically-Excited Hyperfine Structure of Er:YSiO
Sebastian P. Horvath, Jelena V. Rakonjac, Yu-Hui Chen +4
We show that crystal-field calculations for point-group symmetry are possible, and that such calculations can be performed with sufficient accuracy to have substantial utilit…
Current developments of nanoscale insight into corrosion protection by passive oxide films
Vincent Maurice, Philippe Marcus
Oxide passive films are a key for the durability of metals and alloys components as well as a central issue in corrosion science and engineering. Herein, we discuss current develop…
On the use of the IAST method for gas separation studies in porous materials with gate-opening behavior
Guillaume Fraux, Anne Boutin, Alain H. Fuchs +1
Highly flexible nanoporous materials, exhibiting for instance gate opening or breathing behavior, are often presented as candidates for separation processes due to their supposed h…
Recent advances in the computational chemistry of soft porous crystals
Guillaume Fraux, François-Xavier Coudert
Here we highlight recent progress in the field of computational chemistry of nanoporous materials, focusing on methods and studies that address the extraordinary dynamic nature of…