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5 papers · 2 filters
The consequence of excess configurational entropy on fragility: the case of a polymer/oligomer blend
C. Dalle-Ferrier, S. Simon, W. Zheng +5
By taking advantage of the molecular weight dependence of the glass transition of polymers and their ability to form perfectly miscible blends, we propose a way to modify the fragi…
Pearlnecklacelike chain conformation of hydrophobic polyelectrolyte: a SANS study of partially sulfonated polystyrene in water
François Boué, Marie Noelle Spiteri, Claudine Williams
The form factor of partially sulfonated polystyrene PSSNa (degree of sulfonation f =1, 0.72, 0.64 and 0.36), at polymer concentration 0.17M and 0.34M, without or with added salt (0…
Influence of Chain Interdiffusion Between Immiscible Polymers on Dewetting Dynamics
Severine Coppee, Sylvain Gabriele, Alain M. Jonas +2
The interface between two immiscible polymers, polystyrene (PS) and polydimethylsiloxane (PDMS), was studied by neutron reflectivity and dewetting by using free PS chains and PDMS…
Suppression of Aggregation in Natural-Semiflexible/Flexible Polyanion Mixtures, and Direct Check of the OSF Model using SANS
Fabien Bonnet, Ralph Schweins, François Boué +1
Aggregation and other interactions are suppressed for a biological semiflexible polyelectrolyte, hyaluronan (HA), when it is embedded in a mixture with another negatively charged a…
Universal scattering behavior of co-assembled nanoparticle-polymer clusters
J. Fresnais, J. -F. Berret, L. Qi +7
Water-soluble clusters made from 7 nm inorganic nanoparticles have been investigated by small-angle neutron scattering. The internal structure factor of the clusters was derived an…