papers

Publications (61)

astro-ph.EP2023

Phanerozoic biological reworking of the continental carbonate rock reservoir

Craig R. Walton, Oliver Shorttle

Understanding the co-evolution of complex life with Earth's geology is an enduring challenge. The rock record evidences remarkable correlations between changes in biology and the w…

astro-ph.EP2023

Spatially resolving the volatile sulfur abundance in the HD 100546 protoplanetary disk

Luke Keyte, Mihkel Kama, Ko-Ju Chuang +5

Volatile elements play a crucial role in the formation of planetary systems. Their abundance and distribution in protoplanetary disks provide vital insights into the connection bet…

astro-ph.EP2023

A mineralogical reason why all exoplanets cannot be equally oxidising

Claire Marie Guimond, Oliver Shorttle, Sean Jordan +1

From core to atmosphere, the oxidation states of elements in a planet shape its character. Oxygen fugacity (fO) is one parameter indicating these likely oxidation states. The o…

astro-ph.EP2021

Evidence for post-nebula volatilisation in an exo-planetary body

John H. D. Harrison, Oliver Shorttle, Amy Bonsor

The loss and gain of volatile elements during planet formation is key for setting their subsequent climate, geodynamics, and habitability. Two broad regimes of volatile element tra…

astro-ph.EP2025

Tracing the Inner Edge of the Habitable Zone with Sulfur Chemistry

Sean Jordan, Oliver Shorttle, Paul B. Rimmer

The circumstellar liquid-water habitable zone guides our search for potentially inhabited exoplanets, but remains observationally untested. We show that the inner edge of the habit…

astro-ph.EP2023

Photochemically-produced SO in the atmosphere of WASP-39b

Shang-Min Tsai, Elspeth K. H. Lee, Diana Powell +82

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been…

astro-ph.EP2026

Comparative biosignatures with systemic retrievals

Tereza Constantinou, Oliver Shorttle, Miles Cranmer +1

The discovery of inhabited exoplanets hinges on identifying biosignature gases. JWST can reveal biosignature gases, though current discoveries have yet to evidence life. The centra…

astro-ph.EP2024

Cosmic dust fertilization of glacial prebiotic chemistry on early Earth

Craig R. Walton, Jessica K. Rigley, Alexander Lipp +5

Earth's surface is deficient in available forms of many elements considered limiting for prebiotic chemistry. In contrast, many extraterrestrial rocky objects are rich in these sam…

astro-ph.EP2022

Molecular tracers of planet formation in the atmospheres of hot Jupiters

Richard Hobbs, Oliver Shorttle, Nikku Madhusudhan

The atmospheric chemical composition of a hot Jupiter can lead to insights into where in its natal protoplanetary disk it formed and its subsequent migration pathway. We use a 1-D…

astro-ph.EP2024

Impact sculpting of the early martian atmosphere

Oliver Shorttle, Homa Saeidfirozeh, Paul Rimmer +4

Intense bombardment of solar system planets in the immediate aftermath of protoplanetary disk dissipation has played a key role in their atmospheric evolution. During this epoch, e…

astro-ph.EP2021

Photochemistry of Venus-Like Planets Orbiting K- and M-Dwarf Stars

Sean Jordan, Paul B. Rimmer, Oliver Shorttle +1

Compared to the diversity seen in exoplanets, Venus is a veritable astrophysical twin of the Earth, however its global cloud layer truncates features in transmission spectroscopy,…

astro-ph.EP2025

Can tidal evolution lead to close-in planetary bodies around white dwarfs I: Orbital period distribution

Yuqi Li, Amy Bonsor, Oliver Shorttle +1

The evolution of planetary systems around white dwarfs is crucial to understanding the presence of planetary material in the atmospheres of white dwarfs. These systems uniquely pro…

astro-ph.EP2019

Origin of life's building blocks in Carbon and Nitrogen rich surface hydrothermal vents

Paul B Rimmer, Oliver Shorttle

There are two dominant and contrasting classes of origin of life scenarios: those predicting that life emerged in submarine hydrothermal systems, where chemical disequilibrium can…

astro-ph.EP2026

Earth and Mars interior structures set by re-melting of the first solid mantle

Antonio Manjón-Cabeza Córdoba, Maxim D. Ballmer, Oliver Shorttle

Magma ocean crystallisation sets up the early structure and long-term evolution of terrestrial planets. Recent seismic evidence signals the presence of a silicate layer at the base…

astro-ph.EP2026

Beyond the mass-radius plane: Integrated radiative-convective and interior structure simulations of the exoplanet continuum

Harrison Nicholls, Oliver Shorttle, Tim Lichtenberg +1

Static structure models, which map mass-radius constraints to bulk planet composition, are frequently used to categorise exoplanets due to their computational efficiency and the hi…

astro-ph.EP2025

Planetary albedo is limited by the above-cloud atmosphere: Implications for sub-Neptune climate

Sean Jordan, Oliver Shorttle, Sascha P. Quanz

Energy limits that delineate the `habitable zone' for exoplanets depend on a given exoplanet's net planetary albedo (or `Bond albedo'). We here demonstrate that the planetary albed…

astro-ph.EP2023

Growth and Evolution of Secondary Volcanic Atmospheres: II. The Importance of Kinetics

Philippa Liggins, Sean Jordan, Paul B. Rimmer +1

Volcanism is a major and long-term source of volatile elements such as C and H to Earth's atmosphere, likely has been to Venus's atmosphere, and may be for exoplanets. Models simul…

astro-ph.EP2021

Host-star and exoplanet compositions: a pilot study usinga wide binary with a polluted white dwarf

Amy Bonsor, Paula Jofre, Oliver Shorttle +3

Planets and stars ultimately form out of the collapse of the same cloud of gas. Whilst planets, and planetary bodies, readily loose volatiles, a common hypothesis is that they reta…

astro-ph.EP2024

A dry Venusian interior constrained by atmospheric chemistry

Tereza Constantinou, Oliver Shorttle, Paul B. Rimmer

Venus's climatic history provides powerful constraint on the location of the inner-edge of the liquid-water habitable zone. However, two very different histories of water on Venus…

astro-ph.EP2026

Most Rocky Sub-Neptunes are Molten: Mapping the Solidification Shoreline for Gas Dwarf Exoplanets

Robb Calder, Oliver Shorttle, Harrison Nicholls +2

Sub-Neptunes are the most common type of detected exoplanet, yet their observed masses and radii are degenerate with several interior structures. One possibility is that sub-Neptun…

astro-ph.EP2025

Powerful lightning on Venus constrained by atmospheric NO

Tereza Constantinou, Oliver Shorttle, Paul B. Rimmer

Signs of lightning on Venus have long been sought, including by space missions and ground-based telescopes searching for optical flashes, plasma waves, or radio signatures. These e…

astro-ph.IM2021

Ariel Planetary Interiors White Paper

Ravit Helled, Stephanie Werner, Caroline Dorn +10

The recently adopted Ariel ESA mission will measure the atmospheric composition of a large number of exoplanets. This information will then be used to better constrain planetary bu…

astro-ph.EP2022

Prevalence of short-lived radioactive isotopes across exoplanetary systems inferred from polluted white dwarfs

Alfred Curry, Amy Bonsor, Tim Lichtenberg +1

In the Solar System short-lived radioisotopes, such as 26Al, played a crucial role during the formation planetary bodies by providing a significant additional source of heat. Notab…

astro-ph.EP2025

Re-accretion of Giant Impact Ejecta Can Drive Significant Atmospheric Erosion on Terrestrial Planets

Tuhin Ghosh, Mark Wyatt, Oliver Shorttle

Giant impacts, the collisions between planetary embryos, play a crucial role in sculpting the planets and their orbital architectures. Numerical simulations have advanced our under…

physics.ao-ph2022

Enhanced monitoring of atmospheric methane from space over the Permian basin with hierarchical Bayesian inference

Clayton Roberts, Oliver Shorttle, Kaisey Mandel +4

Methane is a strong greenhouse gas, with a higher radiative forcing per unit mass and shorter atmospheric lifetime than carbon dioxide. The remote sensing of methane in regions of…

astro-ph.EP2023

Atmospheres as a Window to Rocky Exoplanet Surfaces

Xander Byrne, Oliver Shorttle, Sean Jordan +1

As the characterization of exoplanet atmospheres proceeds, providing insights into atmospheric chemistry and composition, a key question is how much deeper into the planet we might…

physics.geo-ph2018

The melting column as a filter of mantle trace-element heterogeneity

Tong Bo, Richard F. Katz, Oliver Shorttle +1

The observed variability of trace-element concentration in basaltic lavas and melt inclusions carries information about heterogeneity in the mantle. The difficulty is to disentangl…

astro-ph.EP2023

Mantle mineralogy limits to rocky planet water inventories

Claire Marie Guimond, Oliver Shorttle, John F. Rudge

Nominally anhydrous minerals in rocky planet mantles can sequester oceans of water as a whole, giving a constraint on bulk water inventories. Here we predict mantle water capacitie…

astro-ph.EP2021

Hydroxide salts in the clouds of Venus: their effect on the sulfur cycle and cloud droplet pH

Paul B. Rimmer, Sean Jordan, Tereza Constantinou +4

The depletion of SO and HO in and above the clouds of Venus (45 -- 65 km) cannot be explained by known gas-phase chemistry and the observed composition of the atmosphere. W…

astro-ph.EP2026

The efficient delivery of highly-siderophile elements to the core creates a mass accretion catastrophe for the Earth

Richard J. Anslow, Maylis Landeau, Amy Bonsor +2

The excess abundance of highly siderophile elements (HSEs), as inferred for the terrestrial planets and the Moon, is thought to record a `late veneer' of impacts after the giant im…

astro-ph.EP2023

Post-main sequence thermal evolution of planetesimals

Yuqi Li, Amy Bonsor, Oliver Shorttle

White dwarfs that have accreted planetary materials provide a powerful tool to probe the interiors and formation of exoplanets. In particular, the high Fe/Si ratio of some white dw…

astro-ph.EP2023

The distribution of impactor core material during large impacts on Earth-like planets

Jonathan P. Itcovitz, Auriol S. P. Rae, Thomas M. Davison +2

Large impacts onto young rocky planets may transform their compositions, creating highly reducing conditions at their surfaces and reintroducing highly siderophile metals to their…

astro-ph.EP2018

Cometary impactors on the TRAPPIST-1 planets can destroy all planetary atmospheres and rebuild secondary atmospheres on planets f, g, h

Quentin Kral, Mark C. Wyatt, Amaury H. M. J. Triaud +3

The TRAPPIST-1 system is unique in that it has a chain of seven terrestrial Earth-like planets located close to or in its habitable zone. In this paper, we study the effect of pote…

astro-ph.EP2024

Distinguishing oceans of water from magma on mini-Neptune K2-18b

Oliver Shorttle, Sean Jordan, Harrison Nicholls +2

Mildly irradiated mini-Neptunes have densities potentially consistent with them hosting substantial liquid water oceans (`Hycean' planets). The presence of CO2 and simultaneous abs…

astro-ph.EP2021

Planets or asteroids? A geochemical method to constrain the masses of White Dwarf pollutants

Andrew M. Buchan, Amy Bonsor, Oliver Shorttle +4

Polluted white dwarfs that have accreted planetary material provide a unique opportunity to probe the geology of exoplanetary systems. However, the nature of the bodies which pollu…

astro-ph.EP2023

Prebiosignature Molecules Can Be Detected in Temperate Exoplanet Atmospheres with JWST

Alastair Claringbold, Paul Rimmer, Sarah Rugheimer +1

The search for biosignatures on exoplanets connects the fields of biology and biochemistry to astronomical observation, with the hope that we might detect evidence of active biolog…

astro-ph.EP2020

Can Volcanism Build Hydrogen-Rich Early Atmospheres?

Philippa Liggins, Oliver Shorttle, Paul B. Rimmer

Hydrogen in rocky planet atmospheres has been invoked in arguments for extending the habitable zone via N2-H2 and CO2-H2 greenhouse warming, and providing atmospheric conditions su…

astro-ph.EP2021

Sulfur Chemistry in the Atmospheres of Warm and Hot Jupiters

Richard Hobbs, Paul Rimmer, Oliver Shorttle +1

We present and validate a new network of atmospheric thermo-chemical and photo-chemical sulfur reactions. We use a 1-D chemical kinetics model to investigate these reactions as par…

astro-ph.EP2025

Can tidal evolution lead to close-in planetary bodies around white dwarfs II: volcanism and transits

Yuqi Li, Amy Bonsor, Oliver Shorttle

Planetary material accreted by white dwarfs provides unique insights regarding exoplanetary composition. The evolutionary pathways of planetary bodies around white dwarfs are cruci…

astro-ph.EP2024

A Surface Hydrothermal Source of Nitriles and Isonitriles

Paul B. Rimmer, Oliver Shorttle

Giant impacts can generate transient hydrogen-rich atmospheres, reducing atmospheric carbon. The reduced carbon will form hazes that rain out onto the surface and can become incorp…

astro-ph.SR2024

Host-star and exoplanet composition: Polluted white dwarf reveals depletion of moderately refractory elements in planetary material

Claudia Aguilera-Gómez, Laura K. Rogers, Amy Bonsor +6

Planets form from the same cloud of molecular gas and dust as their host stars. Confirming if planetary bodies acquire the same refractory element composition as their natal disc d…

astro-ph.EP2025

Abiotic Ozone in the Observable Atmospheres of Venus and Venus-like Exoplanets

Robb Calder, Oliver Shorttle, Sean Jordan +2

Ozone is a potential biosignature and disambuguator between Earth-like and Venus-like exoplanets due to its association on Earth with photosynthetically produced oxygen (O). Ho…

astro-ph.EP2022

Blue marble, stagnant lid: Could dynamic topography avert a waterworld?

Claire Marie Guimond, John Rudge, Oliver Shorttle

Topography on a wet rocky exoplanet could raise land above its sea level. Although land elevation is the product of many complex processes, the large-scale topographic features on…

astro-ph.EP2021

Microtextures in the Chelyabinsk impact breccia reveal the history of Phosphorus-Olivine-Assemblages in chondrites

Craig R. Walton, Ioannis Baziotis, Ana Černok +4

The geochemistry and textural associations of chondritic phosphate minerals can provide insights into the geological histories of parental asteroids, but the processes governing th…

astro-ph.EP2022

Chemical Habitability: Supply and Retention of Life's Essential Elements During Planet Formation

Sebastiaan Krijt, Mihkel Kama, Melissa McClure +5

Carbon, Hydrogen, Nitrogen, Oxygen, Phosphorus and Sulfur (CHNOPS) play key roles in the origin and proliferation of life on Earth. Given the universality of physics and chemistry,…

astro-ph.EP2019

Abundant refractory sulfur in protoplanetary disks

Mihkel Kama, Oliver Shorttle, Adam S. Jermyn +5

Sulfur is one of the most abundant elements in the Universe, with important roles in astro-, geo-, and biochemistry. Its main reservoirs in planet-forming disks have previously elu…

astro-ph.EP2025

Constraining exoplanet interiors using observations of their atmospheres

Tim Lichtenberg, Oliver Shorttle, Johanna Teske +1

Astronomical surveys have identified numerous exoplanets with bulk compositions that are unlike the planets of the Solar System, including rocky super-Earths and gas-enveloped sub-…

astro-ph.EP2022

Constraints on the production of phosphine by Venusian volcanoes

William Bains, Oliver Shorttle, Sukrit Ranjan +4

The initial reports of the presence of phosphine in the cloud decks of Venus has led to the suggestion that volcanism was the source of phosphine, through volcanic phosphides eject…

physics.ao-ph2023

Avoiding methane emission rate underestimates when using the divergence method

Clayton Roberts, Rutger IJzermans, David Randell +5

Methane is a powerful greenhouse gas, and a primary target for mitigating climate change in the short-term future due to its relatively short atmospheric lifetime and greater abili…

astro-ph.EP2026

Organosulfur Chemistry on sub-Neptunes: Implications for hazes and biosignatures

Sean Jordan, Shang-Min Tsai, Paul B. Rimmer +1

The organosulfur biosignature gases dimethylsulfide (DMS) and dimethlydisulfide (DMDS) have recently been claimed to be present in the atmosphere of sub-Neptune exoplanet K2-18b, l…

astro-ph.EP2023

Iceline Variations Driven by Protoplanetary Disc Gaps

Madelyn Broome, Oliver Shorttle, Mihkel Kama +1

The composition of forming planets is strongly affected by the protoplanetary disc's thermal structure. This thermal structure is predominantly set by dust radiative transfer and v…

astro-ph.EP2025

Refractory phosphorus in the HD 100546 protoplanetary disk

Mihkel Kama, Oliver Shorttle, Sandipan P. D. Borthakur +5

The phosphorus budget of planets is intertwined with their formation history and is thought to influence their habitability. The chemical reservoirs and volatile \emph{vs} refracto…

astro-ph.EP2024

White dwarf constraints on geological processes at the population level

Andrew M. Buchan, Amy Bonsor, Laura K. Rogers +3

White dwarf atmospheres are frequently polluted by material from their own planetary systems. Absorption features from Ca, Mg, Fe and other elements can provide unique insights int…

astro-ph.EP2022

Ancient and recent collisions revealed by phosphate minerals in the Chelyabinsk meteorite

Craig R. Walton, Oliver Shorttle, Sen Hu +8

The collision history of asteroids is an important archive of inner Solar System evolution. Evidence for these collisions is brought to Earth by meteorites, which can preserve impa…

astro-ph.EP2022

Growth and evolution of secondary volcanic atmospheres: I. Identifying the geological character of hot rocky planets

Philippa Liggins, Sean Jordan, Paul B. Rimmer +1

The geology of Earth and super-Earth sized planets will, in many cases, only be observable via their atmospheres. Here, we investigate secondary volcanic atmospheres as a key base…

astro-ph.EP2023

Azimuthal C/O Variations in a Planet-Forming Disk

Luke Keyte, Mihkel Kama, Alice S. Booth +8

The elemental carbon-to-oxygen ratio (C/O) in the atmosphere of a giant planet is a promising diagnostic of that planet's formation history in a protoplanetary disk. Alongside effo…

astro-ph.EP2022

Proposed energy-metabolisms cannot explain the atmospheric chemistry of Venus

Sean Jordan, Oliver Shorttle, Paul B. Rimmer

Life in the clouds of Venus, if present in sufficiently high abundance, must be affecting the atmospheric chemistry. It has been proposed that abundant Venusian life could obtain e…

astro-ph.EP2024

From stars to diverse mantles, melts, crusts and atmospheres of rocky exoplanets

Claire Marie Guimond, Haiyang Wang, Fabian Seidler +3

This review is focused on describing the logic by which we make predictions of exoplanetary compositions and mineralogies, and how these processes could lead to compositional diver…

astro-ph.IM2021

Ariel: Enabling planetary science across light-years

Giovanna Tinetti, Paul Eccleston, Carole Haswell +313

Ariel, the Atmospheric Remote-sensing Infrared Exoplanet Large-survey, was adopted as the fourth medium-class mission in ESA's Cosmic Vision programme to be launched in 2029. Durin…

astro-ph.EP2026

Equifinality of Venus-like CO Atmospheres

Tereza Constantinou, Oliver Shorttle, Harrison Nicholls

While Earth locks much of its carbon in its crust as carbonates, Venus retains a comparable carbon inventory almost entirely in its atmosphere as CO. On Earth, the geological c…

astro-ph.EP2021

Why Geosciences and Exoplanetary Sciences Need Each Other

Oliver Shorttle, Natalie Hinkel, Cayman Unterborn

The study of planets outside our solar system may lead to major advances in our understanding of the Earth, and provide insight into the universal set of rules by which planets for…